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Quiz 207
Mdcat-past-papers Quiz
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4121. The alkaline hydroxides of bromoethane shown below gives alcohol as the product: CH₃—CH₂—Br → CH₃—CH₂—OH The reagent and the condition used in the reaction is:
H₂O at room temperature
Ethanol, Heat
KOH in alcohol
Dilute NaOH, warm
4122. In substitution reactions, dihaloalkane or secondary halogenoalkane give/show:
SN1 mechanism
SN2 mechanism
Both E1 and E2
Both SN1 and SN2
4123. Consider the reaction given below: Which statement is true?
Reagent for I is KOH in alcohol
Reagent for II is KOH in aqueous solution
Reagent I is debromination
Reaction II is elimination
4124. In the below reaction, the configuration of product is:
100% same of configuration of reactant
50% retained
100% opposite from configuration of reactant
4125. Consider the reaction given below: CH₃CH₂Br → H₂C=CH₂ + HBr Mechanism followed by the reaction is:
E2
E1
SN1
SN2
4126. The species which are produced by heterolytic bond breaking and can act as electron pair donors are known as:
Nucleophiles
Free Radicals
Cations
Anions
4127. Which of the following acts as a nucleophile in the reaction of alkyl halide with alcoholic aqueous solution?
H⁺
NH₃
NO₂
Br⁻
4128. What is the order of increasing reactivity of alkyl halides?
Fluoroalkane > Chloroalkane > Bromoalkane > Iodoalkane
Iodoalkane < Bromoalkane < Chloroalkane < Fluoroalkane
Iodoalkane < Bromoalkane < Chloroalkane < Fluoroalkane
Fluoroalkane < Chloroalkane < Bromoalkane < Iodoalkane
4129. The decomposition of phosphorus pentachloride in the presence of moisture takes place by the following mechanism: PCL5+H2O→POCL3+2HCL (slow step) POCL3+3H2O→H3PO4+3HCL (Fast step) Result = PCL5 +4H2O→ H3PO4+5HCl the rate equation for this reaction will be:
rate =k[PCL5][ H2O]
rate = [PCL5][ H2O]
rate =k[POCL3][ H2O]3
rate =k[PCL5][ H2O]3
4130. In the reaction sequence CH₃−CH₂−CH₂−Br + Alc KOH → C → D, Product D will be:
2-propanol
1-propanol
Propanoic acid
Mixture of methanol and ethanol
4131. Which balanced chemical equation shows the formation of ethyl chloride using thionyl chloride?
CH₃COOH + SOCl₂ → CH₃COCl + SO₂ + HCl
CH₃CH₂COOH + 2SOCl₂ → CH₃CH₂COCl + SO₂ + HCl
CH₃CH₂OH + SOCl₂ → CH₃CH₂Cl + SO₂ + HCl
HCOOH + SOCl₂ + SOCl₂ → HOCl + SO₂ + HCl
4132. The increasing stability order of the following compounds (1) CH₃CH₂CH₂⁺ (2) (CH₃)₃C⁺ (3) CH₃CH₂−CH⁺−CH₃ are:
1 > 2 > 3
2 > 3 > 1
3 > 2 > 1
3 > 1 > 2
4133. When 2-bromopropane reacts with sodium ethoxide, the major product is/are:
Propane
Ethyl isopropyl ether
Propene
All are formed
4134. Identify the correct statement related to substitution and elimination of alkyl halides:
Strong bases cause substitution in preference to elimination
Role of leaving groups in elimination is similar to substitution
Substitution is favored more than elimination by decreasing solvent polarity
Decrease in temperature will favor elimination more than substitution
4135. Alkyl halides involving -C-X bond breakage and -C-Nu bond formation simultaneously would follow which one of the following mechanisms:
SN1
SN2
E1
E2
4136. Alkyl halide, on reaction with NaOH, produces an alkane. Mechanism of reaction is:
SN
Elimination
Decomposition
Addition
4137. SN1 mechanism is a:
Formation of carbocation is fast step
Single step mechanism
Two step mechanism
Attack of nucleophile as carbocation is slow step
4138. The elimination between alkyl halides and strong base takes place by two mechanisms—E1 and E2. How many steps are involved in each one of these?
E1 elimination is two steps & E2 is one step
E1 & E2 both take place in one step
E1 & E2 both take place in two steps
E1 elimination is one step & E2 is two steps
4139. Reactivity order of halogen acids is:
HF > HCl > HBr > HI
HBr > HCl > HI
HCl > HBr > HI > HF
HI > HBr > HCl > HF
4140. Alkyl halides involving -C-X bond breakage and -C-Nu bond formation simultaneously would follow the mechanism:
SN1
SN2
E1
E2
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