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Quiz 213
Mdcat-past-papers Quiz
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4241. Consider the following reaction: R–CHO + 2[Ag(NH₃)₂]OH → R–COOH + 2Ag + H₂O + 2NH₃
Fehling test
Ninhydrin test
Benedict's test
Tollen's test
4242. A student mixed ethyl alcohol with small amount of sodium dichromate and added it to the hot solution of dilute sulphuric acid. A vigorous reaction took place. He distilled the product:
Acetone
Acetic acid
Dimethyl ether
Acetaldehyde
4243. Which of the following is also called silver mirror test?
Fehling's solution
Iodoform test
Tollen's reagent
Benedict's solution
4244. Which one of the following test is given by both aldehyde and ketone?
Silver mirror test
Fehling's solution test
2,4-DNPH test
Benedict's solution test
4245. Propanone can be prepared from propyne by:
Passing a mixture of propyne and steam over a catalyst, Mg at 420°C
Passing a mixture of propyne and ethanol over a catalyst, Zn chromate
Boiling propyne with water in presence of HgSO₄ and H₂SO₄
Treating propyne with iodine and NaOH
4246. Aldehydes react with:
Ketones are more easily oxidized
It is always difficult to oxidize aldehyde
Mild oxidizing agent & strong oxidizing agent both
Only strong oxidizing agent
4247. Addition product of formaldehyde & ethyl alcohol is:
Aldehyde
Acetal
Carboxylic acid
Acetone
4248. Catalytic reduction of aldehyde and ketone forms:
Alcohol
Carboxylic acid
Alkane
Aldehyde
4249. The function of NaOH in Aldol condensation & Cannizzaro's reaction respectively is:
Nucleophile and electrophile
Electrophile and nucleophile
Base and nucleophile
Nucleophile and base
4250. Cannizzaro's reaction is given by:
Formaldehyde
Acetaldehyde
Acetone
Butanone
4251. Acetone reacts with hydrogen cyanide (HCN) to form a cyanohydrin. It is an example of:
Electrophilic addition
Nucleophilic substitution
Electrophilic substitution
Nucleophilic addition
4252. In presence of which of the following, Wolff-Kishner reduction of aldehydes is carried out?
Glycol with KOH
H₂ with Pd
LiAlH₄ in water
Zn-Hg with HCl
4253. Addition of HCN to carbonyl compounds causes the change in hybridization from --- to ---
sp → sp³
sp³ → sp²
sp² → sp³
sp² → sp
4254. In the below reaction, the nucleophile is: HCHO + HCN → OH–CH₂–CN
CN⁻
HCl
Cl⁻
OH⁻
4255. Which group gives a yellow precipitate of triiodomethane when warmed with alkaline aqueous iodine?
Methyl ketone group
Aldehyde group
Carboxyl group
Hydroxyl group
4256. It is a general formula of:
Acetone 2,4-Dinitrophenyl Hydazine
1,3-Dinitrophenyl Hydazone
Phenyl Hydazone
Acetone 2,4-Dinitrophenyl Hydazone
4257. Which one of the following reagents is used to distinguish between aldehydes and ketones?
Alkaline iodine
Tollen's reagent
Bromine
2,4-DNPH
4258. Which type of reaction takes place when a carbonyl compound is taken with a mixture of NaCN and an acid?
Substitution reaction
Electrophilic addition reaction
Nucleophilic addition reaction
Displacement reaction
4259. Aqueous solutions of Iodine and sodium hydroxide were mixed in a round bottom flask at 70°C. Following chemical reaction: 3I₂ + 6NaOH → NaIO₃ + NaI + H₂O This reaction is termed as:
Redox reaction
Free radical reaction
Precipitation reaction
Substitution reaction
4260. Which of the following alcohol can give iodoform reaction?
Methanol
1-Butanol
1-Propanol
Ethanol
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