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Quiz 75
Mdcat-past-papers - UHS Quiz
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Board: UHS |
1481. The decomposition of phosphorus pentachloride in the presence of moisture takes place by the following mechanism: PCL5+H2O→POCL3+2HCL (slow step) POCL3+3H2O→H3PO4+3HCL (Fast step) Result = PCL5 +4H2O→ H3PO4+5HCl the rate equation for this reaction will be:
rate =k[PCL5][ H2O]
rate = [PCL5][ H2O]
rate =k[POCL3][ H2O]3
rate =k[PCL5][ H2O]3
1482. In the reaction sequence CH₃−CH₂−CH₂−Br + Alc KOH → C → D, Product D will be:
2-propanol
1-propanol
Propanoic acid
Mixture of methanol and ethanol
1483. Which balanced chemical equation shows the formation of ethyl chloride using thionyl chloride?
CH₃COOH + SOCl₂ → CH₃COCl + SO₂ + HCl
CH₃CH₂COOH + 2SOCl₂ → CH₃CH₂COCl + SO₂ + HCl
CH₃CH₂OH + SOCl₂ → CH₃CH₂Cl + SO₂ + HCl
HCOOH + SOCl₂ + SOCl₂ → HOCl + SO₂ + HCl
1484. The increasing stability order of the following compounds (1) CH₃CH₂CH₂⁺ (2) (CH₃)₃C⁺ (3) CH₃CH₂−CH⁺−CH₃ are:
1 > 2 > 3
2 > 3 > 1
3 > 2 > 1
3 > 1 > 2
1485. When 2-bromopropane reacts with sodium ethoxide, the major product is/are:
Propane
Ethyl isopropyl ether
Propene
All are formed
1486. Identify the correct statement related to substitution and elimination of alkyl halides:
Strong bases cause substitution in preference to elimination
Role of leaving groups in elimination is similar to substitution
Substitution is favored more than elimination by decreasing solvent polarity
Decrease in temperature will favor elimination more than substitution
1487. Alkyl halides involving -C-X bond breakage and -C-Nu bond formation simultaneously would follow which one of the following mechanisms:
SN1
SN2
E1
E2
1488. An alcohol is converted to an aldehyde with same number of carbon atoms as that of alcohol in the presence of K₂Cr₂O₇/H₂SO₄, the alcohol is:
CH₃Cl(CH)₂ OH
(CH₃)₂CHOH
CH₃CH₂CH₂OH
(CH₃)₃COH
1489. Which enzyme is involved in fermentation of glucose:
Zymase
Invertase
Urease
Diastase
1490. The dehydration of ethyl alcohol with concentrated H₂SO₄ at 140°C gives:
Ethene
Diethyl ether
Alcohol
Carboxylic acid
1491. Ethanol can be converted into ethanoic acid by:
Oxidation
Fermentation
Hydration
Hydrogenation
1492. Alcohol in which carbon atom bonded to OH group is further attached with three alkyl group is:
Tertiary alcohol
Primary alcohol
Aromatic alcohol
Secondary alcohol
1493. Select one which is alcohol:
CH₃−CH₂−Br
CH₃−O−CH₃
CH₃COOH
CH₃−CH₂−OH
1494. Which one of the following compounds is known as tertiary alcohol?
1-Propanol
2-Methyl-2-propanol
2-Methyl-1-propanol
2-Propanol
1495. Which of the following compounds will give a secondary alcohol after reaction with NaBH₄?
CH₃COOCH₃
CH₃COCH₃
CH₃CH₂COOH
CH₃CH₂CHO
1496. Which of the following reactions is used for the production of alcohols on industrial scale?
Hydrogenation of alkenes
Hydroxylation of alkenes
Hydration of alkenes
Hydrohalogenation of alkenes
1497. When ethanol is warmed with ethanoic acid in the presence of a strong acid catalyst, an ester ethanoate is formed. During this reaction:
Alcohol is reduced
O−H bond of ethanoic acid is broken
O−H bond of ethanol is broken
Acid is oxidized
1498. Consider the following reactions: C₂H₅OH + PCl₅ → What products may be formed?
C₂H₅Cl
C₂H₅Cl + HCl
C₂H₅Cl, POCl₃ and HCl
C₂H₅Cl and POCl₃
1499. Primary, Secondary, and Tertiary alcohols can be identified and distinguished by:
Lucas test
Iodoform test
Baeyer's test
Silver mirror test
1500. Which one of the following alcohols is indicated by formation of yellow crystals in the iodoform test?
Methanol
Ethanol
Butanol
Propanol
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