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Quiz 14
Mdcat-past-papers - UHS - Chemistry Quiz
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Board: UHS | Subject: Chemistry |
261. Which mechanism of reactions is shown by carbonyl compounds?
Electrophilic addition
Electrophilic substitution
Free radical substitution
Nucleophilic addition
262. Which of the following would react with ozone in the atmosphere?
F
O₂
O
Cl
263. When halogen is removed from an alkyl halide a carbocation is formed, Identify the most reactive carbocation:
Primary carbocation
Secondary carbocation
Tertiary carbocation
Methyl carbocation
264. Freon is commonly known as:
Refrigerant
A solvent
Insecticides
A fire extinguisher
265. Neopentyl chloride belongs to which class of alkyl halides?
Primary alkyl halides
Secondary alkyl halides
Tertiary alkyl halides
Quaternary alkyl halides
266. In SN1 reaction the correct order of reactivity of alkyl halides is?
Primary > Secondary > Tertiary
Tertiary > Secondary > Primary
Secondary > Primary > Tertiary
Primary > Tertiary > Secondary
267. Identify the correct ascending order of reactivity of alkyl halides:
Cl, Br, I, F
F, Cl, Br, I
Br, I, F, Cl
I, F, Cl, Br
268. When purely alcoholic solution of sodium/potassium hydroxide and halogenoalkanes are reacted an alkene is formed. What is the mechanism of reaction?
Elimination
Dehydration
Debromination
Reduction of benzene
269. The alkaline hydroxides of bromoethane shown below gives alcohol as the product: CH₃—CH₂—Br → CH₃—CH₂—OH The reagent and the condition used in the reaction is:
H₂O at room temperature
Ethanol, Heat
KOH in alcohol
Dilute NaOH, warm
270. In substitution reactions, dihaloalkane or secondary halogenoalkane give/show:
SN1 mechanism
SN2 mechanism
Both E1 and E2
Both SN1 and SN2
271. Consider the reaction given below: Which statement is true?
Reagent for I is KOH in alcohol
Reagent for II is KOH in aqueous solution
Reagent I is debromination
Reaction II is elimination
272. In the below reaction, the configuration of product is:
100% same of configuration of reactant
50% retained
100% opposite from configuration of reactant
273. Consider the reaction given below: CH₃CH₂Br → H₂C=CH₂ + HBr Mechanism followed by the reaction is:
E2
E1
SN1
SN2
274. The species which are produced by heterolytic bond breaking and can act as electron pair donors are known as:
Nucleophiles
Free Radicals
Cations
Anions
275. Which of the following acts as a nucleophile in the reaction of alkyl halide with alcoholic aqueous solution?
H⁺
NH₃
NO₂
Br⁻
276. What is the order of increasing reactivity of alkyl halides?
Fluoroalkane > Chloroalkane > Bromoalkane > Iodoalkane
Iodoalkane < Bromoalkane < Chloroalkane < Fluoroalkane
Iodoalkane < Bromoalkane < Chloroalkane < Fluoroalkane
Fluoroalkane < Chloroalkane < Bromoalkane < Iodoalkane
277. The decomposition of phosphorus pentachloride in the presence of moisture takes place by the following mechanism: PCL5+H2O→POCL3+2HCL (slow step) POCL3+3H2O→H3PO4+3HCL (Fast step) Result = PCL5 +4H2O→ H3PO4+5HCl the rate equation for this reaction will be:
rate =k[PCL5][ H2O]
rate = [PCL5][ H2O]
rate =k[POCL3][ H2O]3
rate =k[PCL5][ H2O]3
278. In the reaction sequence CH₃−CH₂−CH₂−Br + Alc KOH → C → D, Product D will be:
2-propanol
1-propanol
Propanoic acid
Mixture of methanol and ethanol
279. Which balanced chemical equation shows the formation of ethyl chloride using thionyl chloride?
CH₃COOH + SOCl₂ → CH₃COCl + SO₂ + HCl
CH₃CH₂COOH + 2SOCl₂ → CH₃CH₂COCl + SO₂ + HCl
CH₃CH₂OH + SOCl₂ → CH₃CH₂Cl + SO₂ + HCl
HCOOH + SOCl₂ + SOCl₂ → HOCl + SO₂ + HCl
280. The increasing stability order of the following compounds (1) CH₃CH₂CH₂⁺ (2) (CH₃)₃C⁺ (3) CH₃CH₂−CH⁺−CH₃ are:
1 > 2 > 3
2 > 3 > 1
3 > 2 > 1
3 > 1 > 2
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